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81.
《Ceramics International》2022,48(11):15056-15063
Hydrogen (H2) sensors based on metal oxide semiconductors (MOS) are promising for many applications such as a rocket propellant, industrial gas and the safety of storage. However, poor selectivity at low analyte concentrations, and independent response on high humidity limit the practical applications. Herein, we designed rGO-wrapped SnO2–Pd porous hollow spheres composite (SnO2–Pd@rGO) for high performance H2 sensor. The porous hollow structure was from the carbon sphere template. The rGO wrapping was via self-assembly of GO on SnO2-based spheres with subsequent thermal reduction in H2 ambient. This sensor exhibited excellently selective H2 sensing performances at 390 °C, linear response over a broad concentration range (0.1–1000 ppm) with recovery time of only 3 s, a high response of ~8 to 0.1 ppm H2 in a minute, and acceptable stability under high humidity conditions (e. g. 80%). The calculated detection limit of 16.5 ppb opened up the possibility of trace H2 monitoring. Furthermore, this sensor demonstrated certain response to H2 at the minimum concentration of 50 ppm at 130 °C. These performances mainly benefited from the special hollow porous structure with abundant heterojunctions, the catalysis of the doped-PdOx, the relative hydrophobic surface from rGO, and the deoxygenation after H2 reduction. 相似文献
82.
Alexandre
Imperiale Nicolas Leymarie Edouard Demaldent 《International journal for numerical methods in engineering》2020,121(15):3300-3338
Composite laminate structures remain an important family of materials used in cutting-edge industrial areas. Building efficient numerical modeling tools for high-frequency wave propagation in order to represent ultrasonic testing experiments of these materials remains a major challenge. In particular, incorporating attenuation phenomena within anisotropic plies, and thin intermediate isotropic layers between the plies often represent significant obstacles for standard numerical approaches. In our work, we address both issues by proposing a systematic study of the fully discrete propagators associated to the Kelvin-Voigt, Maxwell, and Zener models, and by incorporating effective transmission conditions between plies using the mortar element method. We illustrate the soundness of our approach by proposing intermediate one-dimensional and two-dimensional numerical evidence, and we apply it to a more realistic configuration of a curved laminate composite structure in a three-dimensional setting. 相似文献
83.
针对液晶屏(LCD)导光板表面缺陷检测方法存在漏检率和误检率较高,对产品表面复杂渐变的纹理结构适应性差的问题,提出一种基于改进相干增强扩散(ICED)与纹理能量测度和高斯混合模型(TEM-GMM)的LCD导光板表面缺陷检测方法。首先,构建ICED模型,基于结构张量引入平均曲率流扩散(MCF)滤波,使得相干增强扩散(CED)模型对缺陷的细线状纹理有良好的边缘保持效果,并利用相干性得到缺陷纹理增强和背景纹理抑制的滤波后图像;然后,根据Laws纹理能量测度(TEM)提取图像纹理特征,将图像的背景纹理特征作为离线阶段高斯混合模型(GMM)的训练数据,使用期望最大化(EM)算法估计GMM参数;最后,计算待检测图像各像素的后验概率,并将其作为在线检测阶段缺陷像素的判断依据。实验结果表明,该检测方法在导光颗粒随机、规则两种分布的缺陷图像测试数据组上的漏检率和误检率分别为3.27%、4.32%和3.59%、4.87%。所提检测方法适用范围广,可有效检测出LCD导光板表面划痕、异物、脏污和压伤等类型的缺陷。 相似文献
84.
Patterned photonic crystals with structural colors on textile substrates have attracted a special attention due to the great advantages in application, which currently become a research hot-spot. This study utilized an ink-jet printing technology to prepare high-quality photonic crystal patterns with structural colors on polyester substrates. The self-assembly temperature of poly(styrene-N-methylol acrylamide) (P(St-NMA)) microspheres set to construct photonic crystals were deeply optimized. Moreover, the structural colors of prepared photonic crystal patterns were characterized and evaluated. When the mass fraction of P(St-NMA) microspheres was 1.0 wt.%, the pH value ranged from 5 to 7, and the surface tension was in the range of 63.79 to 71.20 mN/m, inks could present the best print performance. At 60 °C, prepared P(St-NMA) microsphere inks were good for printing to obtain patterned photonic crystals with regular arrangement and beautiful structural colors. Specifically, photonic crystals with different colors could be constructed by regulating the diameter of microspheres in inks, and prepared structural colors exhibited distinct iridescent phenomenon. The present results could provide a theoretical basis for the industrial realization of patterned photonic crystals by ink-jet printing technology. 相似文献
85.
地铁混凝土处于地下空间,容易受到地下水的碳酸性侵蚀;碱集料反应 (AAR)是一种严重的混凝土耐久性问题,既难以发现又难以修补,由两者共同作用引起的混凝土耐久性降低严重影响地铁隧道的正常使用.为研究纳米材料对地铁混凝土在碳酸性侵蚀和AAR共同作用下耐久性的影响,在普通混凝土中掺入适量纳米SiO2和纳米Fe2O3,利用自行研制的碳酸性侵蚀试验箱进行试验,采用碳酸性侵蚀深度、膨胀率和声速作为测试指标来评价纳米混凝土在碳酸性侵蚀和AAR共同作用下的耐久性.试验结果表明:掺入纳米颗粒后,混凝土的膨胀率和侵蚀深度有了明显降低,而声速有了明显提升,说明纳米混凝土的耐久性优于普通混凝土;在182 d龄期时,掺量为2%的纳米SiO2混凝土耐久性改善最明显,侵蚀深度和膨胀率最小,声速最大且声速下降幅度最小;其次是掺量为1%的纳米Fe2O3混凝土.由于纳米颗粒特殊的物理化学性质,改善了混凝土内部的微观结构和孔溶液的化学组成,使碳酸性侵蚀和碱集料反应共同作用下混凝土的耐久性得到了提高. 相似文献
86.
Rakesh K. Upadhyay Marvin Edelman Autar K. Mattoo 《International journal of molecular sciences》2020,21(24)
Lipoxygenases (LOXs) (EC 1.13.11.12) catalyze the oxygenation of fatty acids and produce oxylipins, including the plant hormone jasmonic acid (JA) and its methyl ester, methyl jasmonate (MeJA). Little information is available about the LOX gene family in aquatic plants. We identified a novel LOX gene family comprising nine LOX genes in the aquatic plant Spirodela polyrhiza (greater duckweed). The reduced anatomy of S. polyrhiza did not lead to a reduction in LOX family genes. The 13-LOX subfamily, with seven genes, predominates, while the 9-LOX subfamily is reduced to two genes, an opposite trend from known LOX families of other plant species. As the 13-LOX subfamily is associated with the synthesis of JA/MeJA, its predominance in the Spirodela genome raises the possibility of a higher requirement for the hormone in the aquatic plant. JA-/MeJA-based feedback regulation during culture aging as well as the induction of LOX gene family members within 6 h of salt exposure are demonstrated. 相似文献
87.
Here, highly‐oriented poly(m‐phenylene isophthalamide)/polyacrylonitrile multi‐walled carbon nanotube (PMIA/PAN‐MWCNT) composite nanofiber membranes with excellent mechanical strength and thermal stability are successfully produced using electrospinning. It is demonstrated that the cooperation of multi‐walled carbon nanotubes (MWCNT) and high‐speed rotating collection is beneficial to the acquisition of highly oriented fibers and effectively improves the mechanical strength of the membrane along the orientation direction. Specifically, the tensile stress of poly(m‐phenylene isophthalamide)/polyacrylonitrile (PMIA/PAN) membrane is enhanced significantly from 10.6 to 20.7 MPa, benefiting from the highly oriented alignment of the fibers as well as the reinforcing effect of MWCNTs on the fibers. Furthermore, the stressing process of single fiber and fiber aggregates is carefully simulated, and the influence of MWCNTs on the mechanical properties of PMIA/PAN‐MWCNT membranes is analyzed comprehensively, providing a meaningful auxiliary means for the study of mechanical properties. In addition, the composite nanofiber membrane has the advantages of both PMIA and PAN, possessing high temperature resistance, flame‐retardancy, and chemical stability, for an ideal high‐temperature material. In short, the as‐prepared PMIA/PAN‐MWCNT composite membrane with excellent comprehensive property emerges a promising application in many fields, especially in high‐tech. 相似文献
88.
以碘吸附值为评价指标,活化时间、活化温度和浸渍比为影响因素,采用响应面法试验设计对磷酸活化法制备咖啡渣活性炭的工艺条件进行优化,并通过静态吸附试验研究了不同吸附时间、溶液pH值和吸附温度条件下,活性炭对水溶液中Cr(Ⅵ)吸附性能的影响,最后利用Langmuir、Freundlich吸附等温方程、准一级动力学方程、准二级动力学方程和颗粒内部扩散方程进行拟合。试验结果表明,制备咖啡渣活性炭的最佳工艺条件为活化时间1 h、活化温度498℃、浸渍比1.72;在此条件下活性炭得率为30.4%,碘吸附值为(799±16)mg/g,比表面积为1 006 m2/g,孔容为0.779 cm3/g、微孔孔容为0.051 cm3/g、平均孔径为3.088 nm。较低pH值和较高温度能够促进活性炭对Cr(Ⅵ)的吸附;Langmuir等温方程能够更好地描述活性炭对Cr(Ⅵ)的吸附效果;活性炭对Cr(Ⅵ)的吸附分3个阶段:快速吸附阶段、慢速吸附阶段和吸附平衡阶段,10 min内可完成吸附总量的79%,360 min内达到吸附平衡,该吸附过程符合准二级吸附动力学方程。分析表明咖啡渣活性炭对Cr(Ⅵ)的吸附主要为单分子层的化学吸附。 相似文献
89.
In this study, imidazolium functionalized poly(vinyl alcohol) (PVA) was synthesized by acetalization and direct quaternization reaction. Afterwards, composite anion exchange membranes based on imidazolium‐ and quaternary ammonium‐ functionalized PVA were used for direct methanol alkaline fuel cell applications. 1H NMR and Fourier transform infrared spectroscopy data indicated that imidazole functionalized PVA was successfully synthesized. Inductively coupled plasma mass spectrometry data demonstrated that the imidazolium structure was efficiently obtained by direct quaternization of the imidazole group. Composite anion exchange membranes were fabricated by application of the functionalized PVA solution on the surface of porous polycarbonate (PC) membranes. Fuel cell related properties of all prepared membranes were investigated systematically. The imidazolium functionalized composite membrane (PVA‐Im/PC) exhibited higher ionic conductivity (7.8 mS cm?1 at 30 °C) despite a lower water uptake and ion exchange capacity value compared to that of quaternary ammonium. In addition, PVA‐Im/PC showed the lowest methanol permeation rate and the highest membrane selectivity as well as high alkaline and oxidative stability. Dynamic mechanical analysis results reveal that both composite membranes were mechanically resistant up to 107 Pa at 140 °C. The superior performance of imidazolium functionalized PVA composite membrane compared to quaternary ammonium functionalized membrane makes it a promising candidate for direct methanol alkaline fuel cell applications. © 2020 Society of Chemical Industry 相似文献
90.
针对流程工业生产系统监测数据存在强噪声和混沌性的特点,提出了一种局部投影方法(Local Projection Method)与小波包方法相结合的信号降噪方法。该方法先利用局部投影方法从动力学系统嵌入流形的角度进行多次迭代降噪,并根据关联维数来判定迭代终止;再利用小波包方法从频率的角度进行降噪,抑制高频噪声的干扰,取得了较好的降噪效果。用Lorenz时间序列进行仿真验证,对仿真时间序列加入不同程度的噪声,对比分析小波包、局部投影与该方法降噪后的相空间、SNR值和最大Lyapunov指数,证明了该方法对于中高强度噪声具有更好的降噪效果。并将该方法用于某压缩机组的实际监测数据降噪,评估三种方法的降噪效果,进一步验证了该方法的优越性。 相似文献